Fosfomycin

  • Fosfomycin is synthetic derivative of phosphonic acid. It is broad spectrum antibiotic which is produced from organism Streptomyces fradiae. It is also produced synthetically. 
  • Fosfomycin was discovered in 1969 by researchers of Spanish Penicillin and Antibiotics company. 

Antibacterial spectrum of fosfomycin

  • It exerts bactericidal action against both gram positive and gram-negative pathogens and is active against Staphylococcus aureusS. epidermisEnterococcus faecalis and Enterococcus spp. It is also active against gram-negative pathogens including E. coliKlebsiellaCitrobacter spp., Shigella spp., Salmonella spp., and Proteus mirabilis

Indications of fosfomycin

  • Used in treating uncomplicated case of cystitis or UTI (urinary Tract Infection) caused by susceptible strains of E. coli and Enterococcus faecalis
  • Its off label uses include in treating pyelonephritis or perinephric abscess. 

Mechanism of action of fosfomycin

 Figure- Mechanism of action of Fosfomycin (Source- Candel et al, 2019)

  • It exerts its action by inhibiting bacterial cell wall synthesis. 
  • The enzyme UDP-N-acetylglucosamine enolpyruvyl transferase (MurA) catalyze transfer of enolpyruvyl moiety of PEP (phosphoenolpyruvate) to 3’ hydroxyl group of UDP-N-acetylglucosamine (U-NAG) leading to formation of peptidoglycan precursor, UDP N-acetylmuramic acid (UDP-MurNAc). Fosfomycin binds to thiol group of a cysteine in active site of MurA and inactivates it resulting in inhibition of UDP-MurNAC formation. Hence, the early step of bacterial cell wall synthesis is disrupted. 
  • It also affects adhesion of bacteria to urinary epithelial cells. 

Pharmacokinetics

  • It is well absorbed after oral administration and is also administered by IV route. It is distributed to different tissues including kidney, bladder, lungs, bone, cerebrospinal fluid (CSF) and prostate.
  • Very negligible amount of drug binds to plasma proteins. Majority of administered drug is excreted unchanged in urine and little amount is excreted via feces. 
  • Its half-life is around 4-8 hours. High level in urine persists for more than 48 hours. 
  • It has low molecular weight compound. 

Resistance

  • Bacteria may develop resistance to it by different mechanism like:
    • Decreased uptake of drug by bacteria due to mutation in genes encoding glycerol-3-phosphate transporter or glucose-6-phopshate transporter which are the major transporter of Fosfomycin. 
    • Mutation in binding site of target enzyme, MurA.
    • Inactivation of fosfomycin by enzymatic cleavage of epoxide ring or by phosphorylation of phosphonate group. 
  • Some pathogens like Staphylococcus capitisStaphylococcus saprophylictusMycobacterium tuberculosis and Stenotrophomonas maltophilia are intrinsically resistant to it. 

Adverse effects

  • Some common adverse effects include nausea, headache, diarrhea, and vaginitis. It can also cause rashes, abdominal discomfort, dizziness, drowsiness, and pruritus. 
  • Prolonged use may result in fungal or bacterial superinfection. 

Drug interaction

  • It can interact with drugs like lactobacillus acidophilus, bcg vaccine, cholera vaccine, typhoid vaccine, lactobacillus rhamnosus etc. 

Contraindications

  • Contraindicated in patients with known hypersensitivity to Fosfomycin or other components of the formulation. 
  • It is pregnancy category B drug. 

References

  1. https://go.drugbank.com/drugs/DB00828
  2. https://www.drugs.com/drug-interactions/fosfomycin-with-lactobacillus-acidophilus-1139-0-1424-0.html
  3. Dijkmans AC et al. Fosfomycin: Pharmacological, Clinical and Future Perspectives.  Antibiotics (Basel). 2017 Dec; 6(4): 24.
  4. Falagas ME et al. Fosfomycin. Clin Microbiol Rev. 2016 Apr; 29(2): 321–347.
  5. Candel FJ et al. New perspectives for reassessing fosfomycin: applicability in current clinical practice. Rev Esp Quimioter. 2019 May; 32(Suppl 1): 1–7.
  6. A textbook of clinical pharmacology and therapeutics. 
  7. Lippincott Illustrated Reviews Pharmacology, 6th edition.